Abstract: This study focusses on dose rate determination in complex settings in two drill cores from the site of Niederweningen,Northern Switzerland. A crosscheck with a certified standard material and neutron activation analyses (NAA) reveals an overall good performance of high-resolution gamma spectrometry (HR-GS) when determining dose rate-relevant elements. A second focus is on average water content during burial, by comparing measured sediment moisture with water uptake capability. Furthermore, layer models are used to investigate the impact of inhomogeneous stratification on dose rate. Finally, different scenarios to correct for radioactive disequilibrium in the uranium decay chain are investigated. While most of the applied corrections appear to have only a minor to moderate effect on age calculation, the results for one core are contradictory. Possibly, some of the applied correction scenarios are not reflecting the complex natural setting sufficiently, in particular average sediment moisture during burial and the timing of radioactive disequilibrium might be incorrectly estimated. While deposition in one core can be quite securely attributed to the period 100-70 ka, assigning the sediment sequence in the other core to the time between ca. 130 ka and 90 ka remains to some extent insecure

Abstract: Carbon capture and storage (CCS) technology is routinely cited as a cost effective tool for climate change mitigation. CCS can directly reduce industrial CO2 emissions and is essential for the retention of CO2 extracted from the atmosphere. To be effective as a climate change mitigation tool, CO2 must be securely retained for 10,000 years (10 ka) with a leakage rate of below 0.01% per year of the total amount of CO2 injected. Migration of CO2 back to the atmosphere via leakage through geological faults is a potential high impact risk to CO2 storage integrity. Here, we calculate for the first time natural leakage rates from a 420 ka paleo-record of CO2 leakage above a naturally occurring, faulted, CO2 reservoir in Arizona, USA. Surface travertine (CaCO3) deposits provide evidence of vertical CO2 leakage linked to known faults. U-Th dating of travertine deposits shows leakage varies along a single fault and that individual seeps have lifespans of up to 200 ka. Whilst the total volumes of CO2 required to form the travertine deposits are high, time-averaged leakage equates to a linear rate of less than 0.01%/yr. Hence, even this natural geological storage site, which would be deemed to be of too high risk to be selected for engineered geologic storage, is adequate to store CO2 for climate mitigation purposes

Abstract: The development of coastal dunes is linked to environmental controls such as sea-level variability, climatic conditions, and coastal morphology. Understanding the spatial and temporal variations of dunes is crucial for predicting how coastal landscapes may react to future climate changes and sea-level rise. However, there are very few detailed studies on the longer time-scale evolution (centennial to millennial) of coastal dunes from subtropical and tropical regions. Here, we combine a high-resolution luminescence chronology with sedimentological analyses to study the depositional history of a transverse coastal dune located within the Bang Berd dune field, Western Gulf of Thailand. While luminescence dating of uniform aeolian deposits is normally straight forward, we observe strong variations in the natural dose rate which are likely explained by the enrichment of accessory minerals in some laminae. Deposition of the dune started at least around 3000 years ago and coincides with a regional sea level drop. Sedimentary structures indicate deposition occurring predominantly in relation to the northeasterly winter monsoon. As the sea-level rise and increased storm intensity in the future may lead to stronger erosion along the coast, this study is highlighting the importance of the Bang Berd dune system as natural protection against coastal inundation