This volume reports on the Enrico Fermi School, the first one dedicated to advanced organic materials. The main research results and open problems in science and technology of organic nanostructures have been discussed here - in particular, growth techniques, electronic and optical properties and device applications. The necessary background material has been covered and interdisciplinary aspects have been emphasized with the aim of a unified approach to the basic physical phenomena bridging the gap between standard graduate courses and the state of the art in the field.